s p o n s o r e d   l i n k s


Nomenclature of Inorganic Chemistry - IUPAC Recommendations 2005.pdf

October 12, 2009 · Filed Under Chemistry  · Tags: ,

This Nomenclature of Inorganic Chemistry Red Book was issued by the Division of Chemical Nomenclature and Structure Representation in collaboration with the Division of Inorganic Chemistry.

Taken from Preface: Chemical nomenclature must evolve to reflect the needs of the community that makes use of it. In particular, nomenclature must be created to describe new compounds or classes of compounds; modified to resolve ambiguities which might arise; or clarified where there is confusion over the way in which nomenclature should be used. There is also a need to make nomenclature as systematic and uncomplicated as possible in order to assist less familiar users (for example, because they are only in the process of studying chemistry or are nonchemists who need to deal with chemicals at work or at home). A revision of Nomenclature of Inorganic Chemistry, IUPAC Recommendations 1990 (Red Book I) was therefore initiated in 1998, under the guidance of the IUPAC Commission on Nomenclature of Inorganic Chemistry (CNIC) and then, on the abolition of CNIC in 2001 as part of the general restructuring of IUPAC, by a project group working under the auspices of the Division of Chemical Nomenclature and Structure Representation (Division VIII).

The need to ensure that inorganic and organic nomenclature systems are, as far as possible, consistent has resulted in extensive cooperation between the editors of the revised Red Book and the editors of Nomenclature of Organic Chemistry, IUPAC Recommendations (the revised ‘Blue Book’, in preparation). At present, the concept of preferred IUPAC names (PINs), an important element in the revision of the Blue Book, has not been extended to inorganic nomenclature (though preferred names are used herein for organic, i.e. carboncontaining, compounds when appropriate). A planned future project on inorganic PINs will need to face the problem of choice between the equally valid nomenclature systems currently in use.

The present book supersedes not only Red Book I but also, where appropriate, Nomenclature of Inorganic Chemistry II, IUPAC Recommendations 2000 (Red Book II). One of the main changes from Red Book I is the different organization of material, adopted to improve clarity. Thus, Chapters IR-5 (Compositional Nomenclature, and Overview of Names of Ions and Radicals), IR-6 (Parent Hydride Names and Substitutive Nomenclature), and IR-7 (Additive Nomenclature) deal with the general characteristics of the three main nomenclature systems applied to inorganic compounds. (Note that the notation ‘IR-’ is used to distinguish chapters and sections in the current book from those in Red Book I, prefixed ‘I-’). The next three chapters deal with their application, particularly that of additive nomenclature, to three large classes of compounds: inorganic acids and derivatives (Chapter IR-8), coordination compounds (Chapter IR-9) and organometallic compounds (Chapter IR-10). Overall, the emphasis on additive nomenclature (generalized from the classical nomenclature of coordination compounds) which was already apparent in Red Book I is reinforced here. Examples are even included of organic compounds, from the borderline between inorganic and organic chemistry, which may be conveniently named using additive nomenclature (although their PINs will be different).

One important addition in this book is Chapter IR-10 on Organometallic Compounds. The separation of this material from that on Coordination Compounds (Chapter IR-9) reflects the huge growth in importance of organometallic chemistry and the very different problems associated with the presence of p-bonded ligands. Chapter IR-9 is also considerably changed (cf. Red Book I, Chapter I-10). This revised chapter includes a clarification of the use of the Z and k conventions in coordination and organometallic compounds (Section IR-9.2.4.3); new rules for the ordering of central atoms in names of polynuclear compounds (Section IR-9.2.5.6); the bringing together of sections on configuration (Section IR-9.3) and their separation from those on constitution (Section IR-9.2); and the addition of polyhedral symbols for T-shaped (Section IR-9.3.3.7) and seesaw (Section IR-9.3.3.8) molecules, along with guidance on how to choose between these shapes and those of closely related structures (Section IR-9.3.2.2).

Contents:

  • General Aims, Function and Methods of Chemical Nomenclature [ Introduction ~ History of chemical nomenclature ~ Aims of chemical nomenclature ~ Functions of chemical nomenclature ~ Methods of inorganic nomenclature ~ Changes to previous IUPAC recommendations ~ Nomenclature recommendations in other areas of chemistry ~ References ]
  • Grammar [ Introduction ~ Enclosing marks ~ Hyphens, plus and minus signs, ‘em’ dashes and bond indicators ~ Solidus ~ Dots, colons, commas and semicolons ~ Spaces ~ Elisions ~ Numerals ~ Italic letters ~ Greek alphabet ~ Asterisks ~ Primes ~ Multiplicative prefixes ~ Locants ~ Ordering principles ~ Final remarks ~ References ]
  • Elements [ Names and symbols of atoms ~ Indication of mass, charge and atomic number using indexes (subscripts and superscripts) ~ Isotopes ~ Elements (or elementary substances) ~ Elements in the periodic table ~ References ]
  • Formulae [ Introduction ~ Definitions of types of formula ~ Indication of ionic charge ~ Sequence of citation of symbols in formulae ~ Isotopically modified compounds ~ Optional modifiers of formulae ~ References ]
  • Compositional Nomenclature and Overview of Names of Ions and Radicals [ Introduction ~ Stoichiometric names of elements and binary compounds ~ Names of ions and radicals ~ Generalized stoichiometric names ~ Names of (formal) addition compounds ~ Summary ~ References ]
  • Parent Hydride Names and Substitutive Nomenclature [ Introduction ~ Parent hydride names ~ Substitutive names of derivatives of parent hydrides ~ Names of ions and radicals derived from parent hydrides ~ References ]
  • Additive Nomenclature [ Introduction ~ Mononuclear entities ~ Polynuclear entities ~ Inorganic chains and rings ~ References ]
  • Inorganic Acides and Nomenclatures [ Introduction and overview ~ General principles for systematic naming of acids ~ Additive names ~ Hydrogen names ~ Abbreviated hydrogen names for certain anions ~ Functional replacement names for derivatives of oxoacids ~ References ]
  • Coordinations Compounds [ Introduction ~ Describing the constitution of coordination compounds ~ Describing the configuration of coordination entities ~ Final remarks ~ References ]
  • Organometallic Compounds [ Introduction ~ Nomenclature of organometallic compounds of the transition elements ~ Nomenclature of organometallic compounds of the main group elements ~ Ordering of central atoms in polynuclear organometallic compounds ~ References ]
  • Solids [ Introduction ~ Names of solid phases ~ Chemical composition ~ Point defect (Kro¨ ger–Vink) notation ~ Phase nomenclature ~ Non-stoichiometric phases ~ Polymorphism ~ Final remarks ~ References ]
  • Tables [ Names, symbols and atomic numbers of the elements ~ Temporary names and symbols for elements of atomic number greater than 111 ~ Suffixes and endings ~ Multiplicative prefixes ~ Geometrical and structural affixes ~ Element sequence ~ Ligand abbreviations ~ Structural formulae of selected ligands ~ Names of homoatomic, binary and certain other simple molecules, ions, compounds, radicals and substituent groups ~ Anion names, ‘a’ terms used in substitutive nomenclature and ‘y’ terms used in chains and rings nomenclature ]

This Inorganic Chemistry Red book pdf is available FREE at International of Union Pure and Applied Chemistry website, we merely collect the information, Online Free Ebooks neither affiliated with the author(s), the website and IUPAC brand nor responsible for its content and change of content. (Read our disclaimer here or here before you download the document from the website written above by clicking the below link).

Download free Nomenclature of Inorganic Chemistry - IUPAC Recommendations 2005.pdf (377 pages pdf file, 4.1 MB).

Related posts




You might also be interested in reading:
chemistry, inorganic nomenclature, IUPAC Nomenclature 2005, nomenaclature of coordination compounds(lecture), download reference in inorganic chemistry, iupac recomendations, IUPAC handbook free download, iupac handbook online, inorganic nomenclature 2005
« Prev
Next »

Disclaimer

http://www.onlinefreeebooks.net - provides you collection of links to other websites containing ebooks/manuals/cheatsheets either for computer geeks, technicians, automotive enthusiasts or programmers. We merely take the power of Google Search to find those materials and link to it. NONE OF THOSE MATERIALS ARE HOSTED IN THIS SERVER NOR UPLOADED BY ME IN SOMEONE'S SERVERS.

We are neither affiliated with authors and brands nor responsible for its content and change of content.

Information contained herein is provided "as is" without warranty of any kind, either expressed or implied, including any warranty of merchantability or fitness for a particular purpose. In no event shall ANYONE be held liable for any loss of profit, special, incidental, consequential, or other similar claims.

Comments

Leave a Reply