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Chemical Principles - Third Edition.pdf

October 22, 2009 · Filed Under Chemical Engineering  · Tags: , , , , , , , ,

Chemical Principles - Third Edition: Dickerson, Richard E. and Gray, Harry B. and Haight, Gilbert P (1979) Chemical principles. Third edition. The Benjamin/Cummings Publishing Company, Inc., Menlo Park, CA. ISBN 0805323988.

Contents:

  • Atoms Molecules and Ions
    • The Structure of Atoms
    • Isotopes
    • Molecules
    • Forces Between Molecules
    • Molecules and Moles
    • Ions
    • Ions in Solution
    • Gaseous Ions
  • Conservation of Mass and Energy
    • Atomic Weights, Molecular Weights and Moles
    • Chemical Analyses: Percent Composition and Empirical Formulas
    • Chemical Equations
    • Calculations of Reaction Yields
    • Solutions as Chemical Reagents
    • Heats of Reaction: Conservation of Energy
    • Conservation Principles
  • Gas Laws and the Kinetic Theory
    • Avogadro’s Law
    • The Pressure of a Gas
    • Boyle’s Law Relating Pressure and Volume
    • Charles’ Law Relating Volume and Temperature
    • The Combined Gas Law
    • The Kinetic Molecular Theory of Gases
    • Predictions of the Kinetic Molecular Theory
    • Real Gases and Deviations from the Ideal Gas Law
  • Will it React? An Introduction to Chemical Equilibrium
    • Spontaneous Reactions
    • Equilibrium and the equilibrium Constant
    • General Form of the equilibrium Constant
    • Natural Atomic Weight
    • Units and Equilibrium Constants
    • Equilibria Involving Gases With Liquids or Solids
    • Factors Affecting Equilibrium: Le Chatelier’s Principle
  • Solution Equilibria: Acids and Bases
    • Equilibria in Aqueous Solutions
    • Ionization of Water and the pH Scale
    • Strong and Weak Acids
    • Strong and Weak Bases
    • Solutions of strong Acids and Bases: Neutralization and Titration
    • Equilibria with Weak Acids and Bases
    • Weak Acids and Their Salts
  • Are Atoms Real? From Democritus to Dulong and Petit
    • The Concept of An element
    • Compounds, Combustion and the Conservation of Mass
    • Does Compound have a Fixed Composition
    • John Dalton and Theory of Atoms
    • Equal Numbers in Equal Volumes: Gay-Lussac and Avogadro
    • Cannizzaro and Rational Method of Calculating Atomic Weights
    • Atomic Weights for the Heavy Elements: Dulong and Petit
    • Combining Capacities, “Valence” and Oxidation Number
  • The Periodic Table
    • Early Classification Schemes
    • The Basic of Periodic Classification
    • The Modern Periodic Table
    • Periodicity of Chemical Properties ad Illustrated by Bynary Hydrides and Oxides
  • Quantum Theory and Atomic Structure
    • Rutherford and the Nuclear Atom
    • The Quantization of Energy
    • Bohr’s Theory of the Hydrogen Atom
    • Particles of Light and Waves of Matter
    • The Uncertainty Principle
    • Wave Equations
    • The Hydrogen Atom
    • Many Electron Atoms
  • Electronic Structure and Atomic Properties
    • Buildup of Many Electron Atoms
    • Types of Bonding
    • Electronegativity
  • Oxidation-Reduction and Chemical Properties
    • Oxidation Numbers
    • Oxidation Reduction Reactions
    • Balancing Oxidation-Reduction Equations
    • Redox Titrations
    • Oxidations and Reduction Potentials
    • Chemical Properties: The s-Orbital Metals
    • The Filling of the d Orbitals: Transitions Metals
    • The Filling of f Orbitals: Lanthanides and Actinides
    • The p Orbital o Representative Elements
  • Lewis Structures abd the VSEPR Method
    • Lewis Structures
    • Acidity of Oxyacids
    • The VSEPR Methods and Molecular Geometry
  • Diatomic Molecules
    • Molecular Orbitals
    • Diatomic Molecules with One Type of Atom
    • Diatomic Molecules with Different Atoms
  • Polyatomic Molecules
    • Localized Molecular Orbitals for BeH2, BH3 and CH4
    • Hydrogen in Bridge Bonds
    • Localized-Molecular-Orbital Theory for Molecules with Lone electron Pairs
    • Single and Multiple Bonds in Carbon Compounds
    • Benzene and Delocalized Orbitals
    • Polar and Nonpolar Polyatomic Molecules
    • Molecular Spectroscopy
  • Binding in Solids and Liquids
    • Elemental Molecular Solids
    • Ionic Solids
    • Molecular Solids and Liquids
    • Metals
    • Nonmetallic Network Solids
    • The Framework of the Planet: silicate Minerals
  • Energy and Enthalpy in Chemical Systems
    • Work Heat and Caloric
    • The First Law of Thermodynamics
    • Energy, Enthalpy, Heat Capacity
    • The First Law and Chemical Reactions
    • Bond Energies
  • Entropy, Free Energy and Chemical Reactions
    • Spontaneity, Reversibility and Equilibrium
    • Heat, Energy and Molecular Motion
    • Entropy and Disorder
    • Third-Law entropies and Chemical Intuition
    • Free Energy and Spontaneity in Chemical Reactions
    • Free Energy and Concentration
  • Free Energy and Equilibrium
    • The Properties and Equilibrium
    • Reactions Involving Gases
    • Le Chatelier’s Principle
    • The anatomy of a reactions
  • Equilibria Involving Liquids and Solids
    • Melting, Evaporation and Sublimation
    • Free Energy of Vaporization and Vapor Pressure
    • The Critical Point
    • Phase Diagrams
    • Solutions and Raoult’s Law
    • Colligative Properties
  • Oxidation-Reduction Equilibria and Electrochemistry
    • Harnessing Spontaneous Reactions
    • Electrochemical Cells
    • Cell EMF and Free Energy
    • Half-Reactions and Reduction Potentials
    • The Effect of Concentration on Cell Voltage: The Nernst Equation
    • Solubility Equilibria and Potentials
    • Redox Chemistry Gone Astray: Corrosion
  • Coordination Chemistry
    • Properties of Transition Metal Complexes
    • Nomenclature for Coordination Compounds
    • Theories of Bonding in Coordination Compounds
    • Theories of Bonding in Coordination Complexes
    • Tetrahedral and Square Planar Coordination
    • Equilibria Involving Complex Ions
  • The Special Role of Carbon
    • The Special Talents of Carbon
    • The Chemistry of the Neighbors of Carbon
    • Saturated Hydrocarbons or Alkanes
    • Unsaturated Hydrocarbons
    • Derivatives of Hydrocarbons: Functional Groups
    • Aromatic Compounds
    • Aromatic Compounds and the Absorbtion of Light
    • Carbohydrates
    • Protein and Enzymes
    • The Mechanism of Action of an Enzyme
    • Energy and Metabolism in Living System
  • Rates and Mechanisms of Chemical Reactions
    • What Happens When Molacules React
    • Measurement of Reaction rates
    • Calculating Rate Constants from Molecular Information
    • Complex Reactions
    • Catalys
  • Nuclear Chemistry
    • The Nucleus
    • Nuclear Decay
    • Stability Series
    • Nuclear Reactions
    • Applications of Nuclear Chemistry and Isotopes
  • Appendix 1: The Systems International (SI) of Units
  • Appendix 2: Physical Constants and Conversion Factors
  • Appendix 3: Standard Enthalpies and Free Energies of Formation, and Standard Third Law Entropies at 298 K
  • Appendix 4: Significant Figures and Exponential (Scientific) Notation
  • Appendix 5: A More Exact Treatment of Acid-Base Equilibria
  • Appendix 6: Answer to Odd-Numbered Problems

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